Search results for "Surface conductivity"
showing 10 items of 13 documents
Investigation of TiO<sub>2</sub> Ceramic Surface Conductivity Using Conductive Atomic Force Microscopy
2012
Dense TiO2 (rutile) ceramic samples were prepared by sintering compacts of titanium dioxide anatase powder at 1500 °C for 5h. Sintered samples were polished and annealed in vacuum at 1000 °C for 1h. Structural properties of the samples were studied by X-ray diffraction, polarized light and scanning electron microscopy. The surface topography and local electrical conductivity of the samples were investigated by atomic force microscopy technique under atmospheric conditions. Enhanced electrical conductivity was observed at grain boundaries while the polished, vacuum annealed grains surface showed non-homogeneous conductivity.
Nonlinear hairy layer theory of electrophoretic fingerprinting applied to consecutive layer by layer polyelectrolyte adsorption onto charged polystyr…
1997
The consecutive layer-by-layer adsorption of poly(allylamine hydrochloride) (PAH) and poly(styrenesulfonate) (PSS) on colloidal charged latex particles is investigated by measuring the electrophoretic mobility as a function of pH and ionic strength over a broad range (electrophoretic fingerprinting). Meaningful interpretation of the data required the development of a nonlinear approach to hairy particle electrophoresis including dissociation, adsorption, and association. Steric and electrostatic exclusion of mobile ions from the hairy layer has been considered. Also, the surface conductivity correction is extended to the case of charged hairy layer particles. We deposited up to three polyel…
Kelvin probe force microscopy studies of the charge effects upon adsorption of carbon nanotubes and C 60 fullerenes on hydrogen-terminated diamond
2018
Hydrogen-terminated diamond is known for its unusually high surface conductivity that is ascribed to its negative electron affinity. In the presence of acceptor molecules, electrons are expected to transfer from the surface to the acceptor, resulting in p-type surface conductivity. Here, we present Kelvin probe force microscopy (KPFM) measurements on carbon nanotubes and C60 adsorbed onto a hydrogen-terminated diamond(001) surface. A clear reduction in the Kelvin signal is observed at the position of the carbon nanotubes and C60 molecules as compared with the bare, air-exposed surface. This result can be explained by the high positive electron affinity of carbon nanotubes and C60, resulting…
Changes in Surface Free Energy and Surface Conductivity of Carbon Nanotube/Polyimide Nanocomposite Films Induced by UV Irradiation.
2021
Changes in surface energy and electrical conductivity of polyimide (PI)-based nanocomposite films filled with carbon nanotubes (CNTs) induced by UV exposure are gaining considerable interest in microelectronic, aeronautical, and aerospace applications. However, the underlying mechanism of PI photochemistry and oxidation reactions induced by UV irradiation upon the surface in the presence of CNTs is still not clear. Here, we probed the interplay between CNTs and PIs under UV exposure in the surface properties of CNT/PI nanocomposite films. Changes in contact angles and surface electrical conductivity at the surface of CNT/PI nanocomposite films after UV exposure were measured. The unpaired e…
Surface-state electrons on a hydrogen film. 1. Annealing of the film
1991
We have investigated the surface of thin films (thickness ∼2 µm) of solid H2 between 1.5 and 4.2 K by measuring the ac conductivity of surface-state electrons (SSE). The films were prepared on a glass substrate by quench condensation at 1.5 K and were therefore initially strongly disordered. In fact the surface of the virgin films before any heat treatment was so rough that no current due to SSE could be observed. Annealing the films decreased the surface roughness and gave rise to a thermal-activation-type temperature dependence of the SSE conductivity. By proper heat treatment up to 8 K the activation energy could be reduced to 10kB.
Fluxon dynamics in Li–Al codoped by microwave surface resistance measurements
2010
Abstract The magnetic-field-induced variations of the microwave surface resistance, R s , have been investigated in ceramic Mg1−x(LiAl)xB2, with x in the range 0.1 – 0.4 . The measurements have been performed on increasing and decreasing the DC magnetic field, H 0 , at fixed temperatures. At low temperatures, we have observed a magnetic hysteresis in the R s ( H 0 ) curves in all the investigated samples. On increasing the temperature, the range of H 0 in which the hysteretic behavior is visible shrinks; however, in the sample with x = 0.1 it is present up to temperatures close to T c . We show that the field dependence of R s can be quantitatively justified taking into account the critical…
Solid proton conductors as room-temperature gas sensors
1993
Ammonia-exchanged ceramic samples of beta alumina have been obtained from plasma-dispersed powders. The ionic conductivity is slightly affected by ion exchange, but the surface conductivity for the amonia-exchanged sample drastically changes in the presence of the water and ammonia vapours. The ammonia-doped xerogel of antimonic acid hydrate in the form of a thick film has been tested as a potentiometric ammonia sensor.
CEMS of insulators by use of gas-flow counters
1994
Gas-flow CEMS counters are usually designed in such a manner that the sample to be investigated is inserted into the counter and serves as the backing cathode. If the sample consists of an insulating material, serious problems are expected by charging-up effects similar to those appearing in Maze counters. These problems are discussed in detail. It could be shown by experiments with glass samples that their very low surface conductivity is sufficient to allow a defined operation of such gas-flow CEMS detectors. The electric field strength between the surface of the sample and the anode has to be equal or higher than that between the entrance window and the anode. This can be ensured by an a…
Complex conductivity in high-Tc single crystal superconductors
1994
The electromagnetic surface impedance of single crystal high-T c superconductors has been examined within the framework of the two-fluid model and the hypothesis that the em field modulates the partial concentrations of both normal and condensate fluids. A comparison with experimental data is reported
Depinning frequency in a heavily neutron-irradiated MgB2 sample
2008
The magnetic-field-induced variations of the microwave surface resistance have been investigated in a heavily neutron-irradiated MgB2 sample, in which the irradiation has caused the merging of the two gaps into a single value. The experimental results have been analyzed in the framework of the Coffey and Clem model. By fitting the experimental data, we have determined the field dependence of the depinning frequency, omega_0, at different values of the temperature. Although the pinning is not particularly effective, the value of omega_0 obtained at low temperatures is considerably higher than that observed in conventional low-temperature superconductors.